Highly regio- and stereoselective one-pot synthesis of carbohydrate-based butyrolactones.
نویسندگان
چکیده
The use of manganese(III) acetate allows the direct synthesis of diverse arrays of [4.3.0] bicyclic carbohydrate-based γ-lactone building blocks from glycals. A mechanism to explain the high regio- and stereoselectivity is proposed. The new reaction has the potential to generate libraries for biological screening.
منابع مشابه
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ورودعنوان ژورنال:
- Organic letters
دوره 13 4 شماره
صفحات -
تاریخ انتشار 2011